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Brake fluids.


As mentioned elsewhere on the page, brake fluid does not compress. It's a good job too - if you put your foot on the brake pedal and it went all the way to the floor, you'd be worried. But that's exactly what can happen if you disregard the "health" of your brake fluid.
Brake fluid is hygroscopic - that means it attracts and soaks up water. This is why it comes in sealed containers when you buy it, and why when the crazy guy four doors down offers you some of the 15 gallons of brake fluid he's had in his garage since the war, you should turn him down. The problem with it being hygroscopic is that if it does start to take on water, Bad Things can happen. Pull up a chair and allow me to explain.
Your typical DOT 4 brake fluid (see later for DOT ratings) boils at about 446°F (230°C). Water boils at 212°F (100°C). Imagine your brakes are getting hot because of a long downhill stretch. Whilst the brake fluid is quite OK, the temperature of the brake components might get up over the boiling point of water. If that happens, the water boils out of the brake fluid and forms steam - a compressible gas. Next time you put your foot on the brake, rather than braking, all the pressure in the brake system is taken up with compressing the steam. Your brakes go out, you don't stop.

Getting a little more complex, the boiling point of a liquid goes up with its pressure (Physics 101). So when you step on the brake, the boiling point of the brake fluid might actually go up to 500°F (260°C) and the boiling point of the water content might raise up to 250°F (121°C). This is great, you might think, because now the boiling point is higher than the temperature of the brake fluid. At least it is until you take your foot off the brake again. Now the pressure in the system returns to normal, the boiling points revert to normal and instantly the water boils off into steam again. The symptoms are slightly different now. Under this scenario, the brakes work the first one or two times, but on the third or fourth press, they stop working because now the temperature and pressures have conspired to boil the water.
The worst possible scenario is brake-fade (see right at the top) combined with air in the system. If this has happened to you, then you're likely reading this page from beyond the grave, because in most accidents where weak brakes become no brakes, there aren't any survivors.

D.O.T ratings

All brake fluids are DOT rated. Your owners handbook for your car or motorbike probably tells you to use DOT3 or DOT4 from a sealed container. The DOT ratings are a set of minimum standards the fluid must adhere to in order to get the rating, and thus work in your braking system. The following table shows the various properties of DOT ratings. Remember that the values here are the minimum values. Most manufacturers make sure their product far exceeds minimum ratings.

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